Welcome to the family, and nice ride. You'll enjoy it.
Some things to note:
Excessive idling is a no-no. Plugs your emissions equipment. Keep it to a minimum as much as possible.
Always tow with the towhaul button engaged. Even if it's a piddly little boat. You won't be losing out on anything by using it. I use it when I have a heavy payload in the bed of the truck too.
When towing anything other than small loads, you'll want to use the Manual option on the gear selector and push the + button to go to 5th gear. This will lock out 6th gear. It seems counterintuitive, but your truck will run better with a trailer when it is cruising between 1800 and 2200 rpm. The transmission temps will stay lower when you do this, and the engine won't lug, which will actually get you better economy when you're towing than if you try and let it pull at 1500 rpm. You can use the +/- button to change gears to keep the truck in the desired rpm range. It will shift up on its own to whatever gear you have selected and not go any higher.
You have a turbo brake, and it does a good job. I recommend using it when you are pulling. Your brake pads will thank you.
I highly recommend some sort of top coat sealant for the trucks. Keep it looking purdy.
Everyone has their own mantra when it comes to maintenance schedules. Start by using the truck's indicator for fuel filter life and oil life. When it says to change those, change them. Save a sample of the oil, if you are interested, and send it to somewhere like
Blackstone Labs and have an oil analysis done. They'll tell you what condition it's in and if you should consider altering your change interval. With the fuel filter, I personally don't see a reason to change it any sooner than the truck tells me to, unless I'm experiencing fuel related issues.
If you don't know the general maintenance history of the truck and it has a lot of miles, it wouldn't be the worst thing you could do to replace all the fluids with fresh. Then you have a baseline for when they were all done.
The stock air filter is a pain in the @$$ to change, in my opinion. Be prepared to be mildly annoyed with it.
Things to keep in the truck are your normal items you would keep in any other vehicle. There's not much special attention needed for these trucks.
If you have any questions, it's probably been answered at least twice on this forum, so don't be shy with that search button at the top. They don't charge you extra for too many clicks. If you're having trouble finding the answer, go ahead and ask. A few people will complain about it being asked thousands of times, and a few people will actually try to help; just like any other online forum.
Again, welcome to the dysfunctional family, and enjoy the heck out of that sweet new ride.